Application of coconut fiber (Cocos Nucifera L.) and analysis of granulometry of adsorbents in glycerol purification.
crude glycerin, purification, adsorption, coconut, granulometry
With the increasing production of biodiesel, also increases the supply of its co-product, glycerol. Crude glycerin has significant economic value and can be applied in drug, cosmetic, food and chemical industries in general. However, its commercial use depends directly on its degree of purity, for this reason its purification becomes so relevant, besides minimize the environmental problems due to its accumulation. There are currently effective processes for glycerol refining, however, these technologies are restricted to large plants, as they require high cost and / or high energy consumption. Therefore, the development of simpler and economical methods is indispensable. In this sense, adsorption, due to its low cost and easy application, stands out as a favorable technique for the removal of glycerol contaminants. Given the above, the objective of this work is to evaluate the purification of crude glycerin obtained from soybean oil transesterification, using coconut shell (Cocos nucifera L.) as adsorbent and comparing with activated charcoal. Initially, glycerol will be pre-purified with phosphoric acid to separate free fatty acids and neutralize catalyst residues. Then, an experimental planning will be carried out to evaluate the efficiency of these adsorbents in glycerol purification and to choose the best purification conditions, analyzing different concentrations and contact time, focusing on the standardization of the granulometry of these materials.